Things got worse for Ole Gunnar Solskjaer's team as Anthony Martial was sent off for lashing out at Erik Lamela, and Harry Kane and Son made it 4-1 before halftime.
Koeman had made no secret that he wanted the duo and the failure to sign Garcia leaves Barca looking especially lightweight in central defense, where they only have Gerard Pique and Clement Lenglet, with Ronald Araujo to provide cover.
Kvitova went into the match quickly as she broke her Chinese opponent twice to surge to a 4-0 lead in the opening set, before serving for the set in the eighth game.
Union gained momentum but missed the chance to extend the lead at the half-hour mark after Nico Schlotterbeck pulled wide from tight angle.
The South American zone's 2022 World Cup qualifiers had been scheduled to begin in late March but were postponed amid the escalating health crisis.
Shanxi led 24-16 in the first quarter, seeing Hebei trail by five points before the half break.
River Plate's Armani and his Boca Juniors counterpart Andrada were joined by defenders Lucas Martinez Quarta (River Plate), Gonzalo Montiel (River Plate) and midfielder Eduardo Salvio (Boca Juniors), the Argentinian Football Association (AFA) said.
Although only ranked No. 357 in the world, the 19-year-old Burel has proved herself in junior competitions as the Rennes-born rising star reached two Grand Slam Junior finals and won the silver medal at the Youth Olympic Games in 2018, when she became the junior world No. 1.
Rafael Nadal of Spain hits a return during the men's singles third round match between Rafael Nadal of Spain and Stefano Travaglia of Italy at French Open tennis tournament 2020 at Roland Garros, in Paris, France on Oct. 2, 2020. (Photo by Aurelien Morissard/Xinhua)
The 28-man squad is headed by Barcelona forward Lionel Messi and also includes Juventus attacker Paulo Dybala and Inter Milan striker Lautaro Martinez.
Xinjiang began to take charge of the game back from the locker room on the way to a 19-point advantage after the third quarter.