Nadal, seeded second, lost 6-2, 7-5 to eighth-seeded Schwartzman, who will next play 12th seed Denis Shapovalov of Canada for a spot in the final.
Elsewhere, Eintracht Frankfurt shared the spoils with newly-promoted Arminia Bielefeld following a 1-1 draw. Augsburg downed Union Berlin 3-1 with two late goals, while Freiburg secured a 3-2 victory over newly-promoted Stuttgart. Enditem
The 70th FIFA Congress convened remotely for the first time, as all of the 211 member associations joined via videoconference on Friday.
World no. 9 Stephen Maguire only managed to draw twice and was beaten by Dale 3-1.
At approximately the same time, Thiago arrived in Liverpool to complete his move to the club after the Premier League champions agreed a 30 million euro fee with Bayern Munich earlier in the week.
"You can be sure that I will do everything possible so that the club has a successful season," Neves said in a video posted on social media.
The Spanish team will now entertain the winner of the game between Locomotive Tbilisi and Dinamo Moskva next week in the penultimate qualifying round. Enditem
The Cameroonian added another six minutes later on cross by Harold Preciado. Referee Fu Ming awarded the goal after reviewing VAR.
Competing under a six-round format, the 24-year-old landed at 8.36m in round two, which is the world leading mark of the year. Huang Changzhou ranked second with a personal best of 8.33m in his first attempt.
Stage One involves 32 groups of four players, with the player who tops each group progressing to Stage Two.
The club has splashed cash on 12 new players in the current transfer window including foreigners; Uganda international Tito Okello, Cameroonian midfielder Bertrand Ngafei and Malawian midfielder Andrew Malisero.